Acid rain looks, feels, and tastes just like clean rain. The harm to people from acid rain is not direct. Walking in acid rain, or even swimming in an acid lake, is no more dangerous than walking or swimming in clean water. The air pollution that causes acid rain is more damaging to human health. Sulfur dioxide and nitrogen oxides, the major sources of acid rain, can irritate or even damage our lungs.
The pollutants that cause acid rain can also reduce visibility, limiting how far into the distance we can see. The primary pollutants associated with acid rain and poor visibility are human-made sulfur dioxide emissions. These emissions form small sulfate particles, or aerosols, in the atmosphere. These aerosols reduce visibility by scattering light. Sulfate aerosols are the main cause of poor visibility in the eastern United States.
Nitrogen oxide emissions are also associated with the acid rain problem. They, too, can form aerosols in the atmosphere that significantly reduce visibility. Nitrate aerosols are often the main cause for poor visibility in the western United States where sulfur dioxide emissions and humidity are lower than in the east.
Making Acid in the Air
The final concentration of acids
(mainly sulfuric acid, H2SO4 and nitric/nitrous
acid, HNO3/HNO2) in precipition (acidity) is
dependent on emissions of SO2 and NOx from
sources, weather conditions andother chemicals present in the
atmoshpere. The formation of sulfuric and nitric/nitrous acid
in the atmosphere is a complex process involving several chemical
reactions involving both solution and gas phase
reactions.
The equilibrium concentraions for the above reactions are dependent upon such things as pH, droplet size, the "sticking coefficient" for SO2 on water, etc. |
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The dominant oxidation process occurs by hydrogen peroxide (formed in the gas phase from free radicals). The reaction involves the formation of an intermediate (A-), possibly a peroxymonosulfurous acid ion |
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2) A- + H+® H2SO4 The dominant oxidation process occurs by hydrogen peroxide (formed in the gas phase from free radicals). The reaction involves the formation of an intermediate (A-), possibly a peroxymonosulfurous acid ion |
NOx
the principal contributor to the formation of nitric acid is the reaction with hydroxy radicals. These radicals are highly reactive and abundant in the atmosphere. |
1. 2NO2(g) +
H2O(l)®
2H+ + NO3- +
NO2- 2. NO(g) + NO2(g) + H2O(l)® 2H+ + 2NO2- 3. 3NO2(g) + H2O(l)® 2H+ + 2NO3- + NO(g) |